A Novel Multifunctional p-Type Semiconductor@MOFs Nanoporous Platform for Simultaneous Sensing and Photodegradation of Tetracycline

被引:140
作者
Gao, Yuan [1 ]
Wu, Jiafei [1 ]
Wang, Jiaqi [1 ]
Fan, Yuxin [1 ]
Zhang, Shiya [1 ]
Dai, Wei [1 ]
机构
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Minist Educ Adv Catalysis Mat, Key Lab, Jinhua 321004, Zhejiang, Peoples R China
关键词
p-type semiconductor; MOFs; CuBi2O4@ZIF-8; fluorescence; photodegradation; METAL-ORGANIC FRAMEWORK; ENHANCED PHOTOCATALYTIC PERFORMANCE; HYDROTHERMAL SYNTHESIS; CUBI2O4; WATER; DEGRADATION; ZIF-8; GAS; ANTIBIOTICS; NANOFLOWERS;
D O I
10.1021/acsami.9b23314
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
p-Type semiconductors enable new opportunities for the development of photocatalysts. Metal-organic frameworks (MOFs) could now be manufactured for a wide range of applications. The zeolitic imidazolate framework-8 (ZIF-8), in particular, shows important desirable properties like good stability and a high surface area. Considering the p-type semiconducting intrinsic catalytic performance of CuBi2O4 (CBO) and the unique porous nanostructure and stability of ZIF-8, in this paper, we innovatively propose and investigate a new p-type semiconductor@MOFs (CBO@ZIF-8) material. Moreover, we focus on its application as a novel dual-function platform for simultaneous detection and degradation. The experimental results reveal that the platform is well suited for absorption, degradation, and fluorescent detection of certain targets. Using the contaminant, antibiotic tetracycline, as an example, the platform confirms excellent fluorescence sensing performance and good photodegradation properties under visible light. These results could aid the future design and implementation of novel and more sophisticated multifunction p-type semiconductor@MOFs platforms. The presented strategy represents the early stages of a future, genuine, general, multifunction platform.
引用
收藏
页码:11036 / 11044
页数:9
相关论文
共 43 条
[1]   CuBi2O4 single crystal nanorods prepared by hydrothermal method: Growth mechanism and optical properties [J].
Abdulkarem, A. M. ;
Li, Jialin ;
Aref, A. A. ;
Ren, Lu ;
Elssfah, E. M. ;
Wang, Hui ;
Ge, Yunke ;
Yu, Ying .
MATERIALS RESEARCH BULLETIN, 2011, 46 (09) :1443-1450
[2]   Antibiotics and antibiotic resistance in water environments [J].
Baquero, Fernando ;
Martinez, Jose-Luis ;
Canton, Rafael .
CURRENT OPINION IN BIOTECHNOLOGY, 2008, 19 (03) :260-265
[3]   A type-II semiconductor (ZnO/CuS heterostructure) for visible light photocatalysis [J].
Basu, Mrinmoyee ;
Garg, Neha ;
Ganguli, Ashok K. .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (20) :7517-7525
[4]   Carbon-Based Photocathode Materials for Solar Hydrogen Production [J].
Bellani, Sebastiano ;
Antognazza, Maria Rosa ;
Bonaccorso, Francesco .
ADVANCED MATERIALS, 2019, 31 (09)
[5]   A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].
Chen, BL ;
Liang, CD ;
Yang, J ;
Contreras, DS ;
Clancy, YL ;
Lobkovsky, EB ;
Yaghi, OM ;
Dai, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393
[6]   Adsorption Behaviors of Organic Micropollutants on Zirconium Metal-Organic Framework UiO-66: Analysis of Surface Interactions [J].
Chen, Caiqin ;
Chen, Dezhi ;
Xie, Shasha ;
Quan, Hongying ;
Luo, Xubiao ;
Guo, Lin .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (46) :41043-41054
[7]   Solid-state synthesis of CuBi2O4/MWCNT composites with enhanced photocatalytic activity under visible light irradiation [J].
Chen, Minmin ;
Yang, Qingya ;
Li, Longfeng ;
Liu, Mingzhu ;
Xiao, Peipei ;
Zhang, Maolin .
MATERIALS LETTERS, 2016, 171 :255-258
[8]   Grain boundary engineering in organic-inorganic hybrid semiconductor ZnS(en)0.5 for visible-light photocatalytic hydrogen production [J].
Feng, Wenhui ;
Fang, Zhibin ;
Wang, Bo ;
Zhang, Lulu ;
Zhang, Yan ;
Yang, Yu ;
Huang, Mianli ;
Weng, Sunxian ;
Liu, Ping .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (04) :1387-1393
[9]   Significantly enhanced visible light photocatalytic efficiency of phosphorus doped TiO2 with surface oxygen vacancies for ciprofloxacin degradation: Synergistic effect and intermediates analysis [J].
Feng, Xianyong ;
Wang, Peifang ;
Hou, Jun ;
Qian, Jin ;
Ao, Yanhui ;
Wang, Chao .
JOURNAL OF HAZARDOUS MATERIALS, 2018, 351 :196-205
[10]   Study on highly enhanced photocatalytic tetracycline degradation of type II AgI/CuBi2O4 and Z-scheme AgBr/CuBi2O4 heterojunction photocatalysts [J].
Guo, Feng ;
Shi, Weilong ;
Wang, HuiBo ;
Han, Mumei ;
Guan, Weisheng ;
Huang, Hui ;
Liu, Yang ;
Kang, Zhenhui .
JOURNAL OF HAZARDOUS MATERIALS, 2018, 349 :111-118