Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water

被引：104
|
作者：
Federsel, Christopher [2 ]
Jackstell, Ralf [2 ]
Boddien, Albert [1 ,2 ]
Laurenczy, Gabor [1 ]
Beller, Matthias [2 ]
机构：
[1] Ecole Polytech Fed Lausanne, Inst Sci Ingn Chim, CH-1015 Lausanne, Switzerland
[2] Univ Rostock, Leibniz Inst Katalyse eV LIKAT, D-18059 Rostock, Germany
来源：
CHEMSUSCHEM | 2010年 / 3卷 / 09期
基金：
瑞士国家科学基金会;
关键词：
carbon dioxide; catalysis; hydrogenation; ruthenium; water; FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; STORAGE MATERIAL; GENERATION; COMPLEXES; FORMATE; REDUCTION;
D O I：
10.1002/cssc.201000151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogenation of bicarbonate in water is achieved by using a ruthenium-based catalytic system. In the presence of dppm as ligand improved yields and catalyst TONs compared to previously known catalyst systems are achieved. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1048 / 1050
页数：3
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