Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water

被引：105

作者：

Federsel, Christopher ^{[2
]}

Jackstell, Ralf ^{[2
]}

Boddien, Albert ^{[1
,2
]}

Laurenczy, Gabor ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Univ Rostock, Leibniz Inst Katalyse eV LIKAT, D-18059 Rostock, Germany

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 09期

基金：

瑞士国家科学基金会;

关键词：

carbon dioxide; catalysis; hydrogenation; ruthenium; water; FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; STORAGE MATERIAL; GENERATION; COMPLEXES; FORMATE; REDUCTION;

D O I：

10.1002/cssc.201000151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation of bicarbonate in water is achieved by using a ruthenium-based catalytic system. In the presence of dppm as ligand improved yields and catalyst TONs compared to previously known catalyst systems are achieved. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1048 / 1050

页数：3

共 43 条

[1]

[Anonymous], 2008, ANGEW CHEM-GER EDIT

[2]

ARESTAL M, 1998, CARBON DIOXIDE RECOV, P407

[3] Continuous Hydrogen Generation from Formic Acid: Highly Active and Stable Ruthenium Catalysts [J].

Boddien, Albert ;

Loges, Bjoern ;

Junge, Henrik ;

Gaertner, Felix ;

Noyes, James R. ;

Beller, Matthias .

ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (14-15) :2517-2520

[4] Hydrogen Generation at Ambient Conditions: Application in Fuel Cells [J].

Boddien, Albert ;

Loges, Bjoern ;

Junge, Henrik ;

Beller, Matthias .

CHEMSUSCHEM, 2008, 1 (8-9) :751-758

[5] The slowest water exchange at a homoleptic mononuclear metal center: Variable-temperature and variable-pressure O-17 NMR study on [Ir(H2O)(6)](3+) [J].

Cusanelli, A ;

Frey, U ;

Richens, DT ;

Merbach, AE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (22) :5265-5271

[6] Homogeneous hydrogenation of carbon dioxide and bicarbonate in aqueous solution catalyzed by water-soluble ruthenium(II) phosphine complexes [J].

Elek, J ;

Nádasdi, L ;

Papp, G ;

Laurenczy, G ;

Joó, F .

APPLIED CATALYSIS A-GENERAL, 2003, 255 (01) :59-67

[7] Carbon Dioxide-The Hydrogen-Storage Material of the Future? [J].

Enthaler, Stephan .

CHEMSUSCHEM, 2008, 1 (10) :801-804

[8] State-of-the-Art Catalysts for Hydrogenation of Carbon Dioxide [J].

Federsel, Christopher ;

Jackstell, Ralf ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (36) :6254-6257

[9]

Fellay C., 2008, Angew. Chem, V120, P4030, DOI DOI 10.1002/ANGE.200800320

[10] A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst [J].

Fellay, Celine ;

Dyson, Paul J. ;

Laurenczy, Gabor .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (21) :3966-3968

← 1 2 3 4 5 →