Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water

被引：104

作者：

Federsel, Christopher ^{[2
]}

Jackstell, Ralf ^{[2
]}

Boddien, Albert ^{[1
,2
]}

Laurenczy, Gabor ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Univ Rostock, Leibniz Inst Katalyse eV LIKAT, D-18059 Rostock, Germany

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 09期

基金：

瑞士国家科学基金会;

关键词：

carbon dioxide; catalysis; hydrogenation; ruthenium; water; FORMIC-ACID DECOMPOSITION; CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; STORAGE MATERIAL; GENERATION; COMPLEXES; FORMATE; REDUCTION;

D O I：

10.1002/cssc.201000151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation of bicarbonate in water is achieved by using a ruthenium-based catalytic system. In the presence of dppm as ligand improved yields and catalyst TONs compared to previously known catalyst systems are achieved. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1048 / 1050

页数：3

共 43 条

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