Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]- κ4O:O′;κ3O,O′:O;κ3O:O,O′bis{[2-(3,4-dimethoxyphenyl)acetato- κ2O,O′](1,10-phenanthroline-κ2N,N′)samarium(III)}

被引：0

作者：

Liu, Jia-Lu

Li, Hua-Qiong

Zhao, Guo-Liang ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

D O I：

10.1107/S1600536810037153

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric dinuclear title complex, [Sm-2-( C10H11O4)(6)(C12H8N2)(2)], the Sm-III ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis- chelating 1,10phenanthroline (phen) ligand, forming a distorted tricapped trigonal- prismatic environment. The DMPA ligands coordinate in bis- chelate, bridging and bridging tridentate modes. An intramolecular C-H center dot center dot center dot O hydrogen bond occurs. Intermolecular C-H center dot center dot center dot O interactions are also present in the crystal.

引用

页码：M1377 / U398

页数：17

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