Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

被引：16

作者：

Benito, Quentin ^{[1
]}

Balogh, Cristina M. ^{[1
]}

El Moll, Hani ^{[1
]}

Gacoin, Thierry ^{[1
]}

Cordier, Marie ^{[2
]}

Rakhmatullin, Aydar ^{[3
]}

Latouche, Camille ^{[4
]}

Martineau-Corcos, Charlotte ^{[3
,5
]}

Perruchas, Sandrine ^{[1
,4
]}

机构：

[1] Ecole Polytech, CNRS, Lab Phys Mat Condensee PMC, F-91128 Palaiseau, France

[2] Ecole Polytech, CNRS, LCM, F-91128 Palaiseau, France

[3] CNRS, CEMHTI, UPR 3079, 1D Ave Rech Sci, F-45071 Orleans 2, France

[4] Inst Mat Nantes, 2 Rue Houssiniere, F-44322 Nantes 3, France

[5] Univ Versailles St Quentin Yvelines UVSQ, MIM, ILV, CNRS,UMR 8180, 45 Ave Etats Unis, F-78035 Versailles, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 71期

关键词：

copper; luminescence; molecular rotor; solvatochromism; vapochromism; COORDINATION POLYMERS; METAL-COMPLEXES; CLUSTER; SENSOR;

D O I：

10.1002/chem.201804377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2I2(Ph2PC2(C6H4)C2PPh2)(3)] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.

引用

页码：18868 / 18872

页数：5

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