Galvanic corrosion between the constituent phases in duplex stainless steel

被引:179
作者
Tsai, Wen-Ta [1 ]
Chen, Jhen-Rong [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
关键词
duplex stainless steel; potentiostatic etching; acid corrosion; selective dissolution; galvanic corrosion;
D O I
10.1016/j.corsci.2007.03.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The exclusive single-phase with the exact chemical composition of the constituent phase in 2205 duplex stainless steel (DSS) could be prepared using selective dissolution method. The respective electrochemical behavior of each constituent phase could then be measured. The experimental results showed that the two distinct peaks in the active-to-passive transition region of the polarization curve determined in 2 M H2SO4 + 0.5 M HCl mixed solution were actually corresponded to the respective anodic peaks of the single austenite and ferrite phases. A polarity reversion was found between austenite and ferrite phases in mixed H2SO4 + HCl solution and HNO3 solution. Galvanic current measurements also revealed that austenite was anode in HNO3 solution, but became cathode when exposed in 2 M H2SO4 + 0.5 M HCl mixed solution. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3659 / 3668
页数:10
相关论文
共 15 条
[1]   In situ local dissolution of duplex stainless steels in 1 M H2SO4+1 M NaCl by electrochemical scanning tunneling microscopy [J].
Femenia, M ;
Pan, J ;
Leygraf, C .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (06) :B187-B197
[2]   In situ study of selective dissolution of duplex stainless steel 2205 by electrochemical scanning tunnelling microscopy [J].
Femenia, M ;
Pan, J ;
Leygraf, C ;
Luukkonen, P .
CORROSION SCIENCE, 2001, 43 (10) :1939-1951
[3]   Chloride-induced stress corrosion cracking of powder metallurgy duplex stainless steels [J].
Laitinen, A ;
Hanninen, H .
CORROSION, 1996, 52 (04) :295-306
[4]  
LIOU HY, 2001, J MATER ENG PERFORM, V10, P213
[5]   Effect of electrolyte composition on the active-to-passive transition behavior of 2205 duplex stainless steel in H2SO4/HCl solutions [J].
Lo, IH ;
Fu, Y ;
Lin, CJ ;
Tsai, WT .
CORROSION SCIENCE, 2006, 48 (03) :696-708
[6]   A corrosion study of the main constituent phases of AZ91 magnesium alloys [J].
Mathieu, S ;
Rapin, C ;
Steinmetz, J ;
Steinmetz, P .
CORROSION SCIENCE, 2003, 45 (12) :2741-2755
[7]   Effects of aging at 475○C on corrosion properties of tungsten-containing duplex stainless steels [J].
Park, CJ ;
Kwon, HS .
CORROSION SCIENCE, 2002, 44 (12) :2817-2830
[8]  
SchmidtRieder E, 1996, BRIT CORROS J, V31, P139
[9]   EFFECTS OF NITROGEN ON THE SELECTIVE DISSOLUTION OF A DUPLEX STAINLESS-STEEL [J].
SRIDHAR, N ;
KOLTS, J .
CORROSION, 1987, 43 (11) :646-651
[10]   GALVANIC EFFECTS ON THE ACTIVE DISSOLUTION OF DUPLEX STAINLESS-STEELS [J].
SYMNIOTIS, E .
CORROSION, 1990, 46 (01) :2-12