Porous polyurethane/acrylate polymer electrolytes prepared by emulsion polymerization

被引：10

作者：

Huang, XB ^{[1
]}

Ren, TB ^{[1
]}

Tang, XZ ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

MATERIALS LETTERS | 2003年 / 57卷 / 26-27期

关键词：

polyurethane/acrylate; emulsion polymerization; polymer electrolytes; morphology; electron microscopy; porosity;

D O I：

10.1016/S0167-577X(03)00286-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Using a new method: emulsion polymerization, a novel polyurethane/acrylate (PUA) porous polymer was prepared. Compared with traditional phase inversion method, the new method can eliminate the pollution produced in process of plasticizer extraction and decrease the cost of production. The porous polymers were immerged in l mol. kg(-1) solution of LiClO4/PC to form polymer electrolytes. The structures of porous polymers and porous polymer electrolytes were observed with SEM. The conductivity of the polymer electrolytes was found to be as high as 10(-3) S cm(-1) which could be useful in many practical electrochemical devices. At the same time, the conductive mechanism of porous gel electrolytes with different liquid content was discussed. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：4182 / 4186

页数：5

共 11 条

[1] Polyphosphazenes with novel architectures: Influence on physical properties and behavior as solid polymer electrolytes [J].

Allcock, HR ;

Sunderland, NJ ;

Ravikiran, R ;

Nelson, JM .

MACROMOLECULES, 1998, 31 (23) :8026-8035

[2] Synthesis and characterization of novel urethane cross-linked ormolytes for solid-state lithium batteries [J].

Bermudez, VD ;

Alcácer, L ;

Acosta, JL ;

Morales, E .

SOLID STATE IONICS, 1999, 116 (3-4) :197-209

[3] Structure and transport properties of polymer gel electrolytes based on PVdF-HFP and LiN(C2F5SO2)2 [J].

Capiglia, C ;

Saito, Y ;

Kataoka, H ;

Kodama, T ;

Quartarone, E ;

Mustarelli, P .

SOLID STATE IONICS, 2000, 131 (3-4) :291-299

[4] Role of PVME on the ionic conductivity and morphology of a TPU based electrolyte [J].

Digar, M ;

Wen, TC .

POLYMER, 2001, 42 (01) :71-81

[5]

Kim JW, 1998, J APPL POLYM SCI, V69, P1079, DOI 10.1002/(SICI)1097-4628(19980808)69:6<1079::AID-APP4>3.0.CO

[6]

2-D

[7]

MacCallum J R, 1989, POLYM ELECTROLYTE, V1, P1

[8] Structure and performance of porous polymer electrolytes based on P(VDF-HFP) for lithium ion batteries [J].

Shi, Q ;

Yu, MX ;

Zhou, X ;

Yan, YS ;

Wan, CR .

JOURNAL OF POWER SOURCES, 2002, 103 (02) :286-292

[9] Composite polymer electrolyte for Li-ion battery [J].

Wang, T ;

Xu, F ;

Cheng, Y ;

Jiang, ZY .

CHEMICAL PHYSICS LETTERS, 2002, 359 (3-4) :303-308

[10] The effect of DMPA units on ionic conductivity of PEG-DMPA-IPDI waterborne polyurethane as single-ion electrolytes [J].

Wen, TC ;

Wang, YJ ;

Cheng, TT ;

Yang, CH .

POLYMER, 1999, 40 (14) :3979-3988

← 1 2 →