Enzymatic synthesis of 4-OH-benzoic acid from phenol and CO2:: The first example of a biotechnological application of a carboxylase enzyme.

被引：43
作者：
Aresta, M
Quaranta, E
Liberio, R
Dileo, C
Tommasi, I
机构：
[1] Univ Bari, Dept Chem, I-70126 Bari, Italy
[2] Unit Taranto, Fac Environm Sci, METEA Res Ctr, I-74100 Taranto, Italy
来源：
TETRAHEDRON | 1998年 / 54卷 / 30期
关键词：
D O I：
10.1016/S0040-4020(98)00475-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
4-OH benzoic acid has been synthesized from phenol and CO2 at room temperature and sub-atmospheric pressure of CO2 with 100 % selectivity, using a Carboxylase enzyme. A cheap, fast and easy method for the phosphorylation of phenol has been also developed. This represents the first biotechnological application of a Carboxylase enzyme. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
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页码：8841 / 8846
页数：6
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