Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal -Organic Frameworks Incorporating Ru(2,2′-bpy)3 photosensitizer

被引:19
作者
Zhang, Xiaobang [1 ]
Wei, Xiaomei [1 ]
Huang, Sheng-Li [1 ]
Yang, Guo-Yu [1 ]
机构
[1] Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci Photoelect Electrophoton, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Rare-earth metal-organic frameworks; Ru(N<^>N)(3) photosensitizer; photocatalysis; sulfide oxidation; POROUS MATERIALS; REDUCTION; OXYGEN;
D O I
10.1002/asia.202100482
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three isostructural lanthanide metal-organic frameworks (Ln-MOFs) were synthesized with uncoordinated N<^>N site, and the Ru(N<^>N)(3) photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.
引用
收藏
页码:2031 / 2034
页数:4
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