Olefin metathesis mediated by: Schiff base Ru-alkylidenes Ru-alkylidenes bearing unsymmetrical NHC ligands

被引:0
作者
Monsaert, Stijn [1 ]
Ledoux, Nele [1 ]
Allaert, Bart [1 ]
Drozdzak, Renata [1 ]
Van Der Voort, Pascal [1 ]
Verpoort, Francis [1 ]
机构
[1] Univ Ghent, Dept Inorgan & Phys Chem, Organomet & Catalysis Div, Krijgslaan 281 S-3, B-9000 Ghent, Belgium
来源
METATHESIS CHEMISTRY: FROM NANOSTRUCTURE DESIGN TO SYNTHESIS OF ADVANCED MATERIALS | 2007年 / 243卷
关键词
olefin metathesis; ruthenium; asymmetrical N-heterocyclic carbene; Schiff-base; alkylidene; DCPD;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The classic Grubbs second-generation complex 2 was modified through 1. The introduction of a bidentate Schiff base ligand 2. Changes in the amino side groups of the NHC ligand Representative olefin metathesis test reactions show the effects induced by the ligand modifications and demonstrate some interesting new properties of the described catalysts. catalysts.
引用
收藏
页码:251 / +
页数:4
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