Studies on Liquid-Liquid Extraction of Yttrium and Separation from Other Rare Earth Elements Using Bifunctional Ionic Liquids

被引:31
作者
Devi, Niharbala [1 ]
Sukla, Lala Behari [1 ]
机构
[1] Siksha O Anusandhan Univ, Inst Tech Educ & Res, Biofuels & Bioproc Res Ctr, G Block, Bhubaneswar 751030, Odisha, India
来源
MINERAL PROCESSING AND EXTRACTIVE METALLURGY REVIEW | 2019年 / 40卷 / 01期
关键词
Yttrium; A336/Cy272; Cyphos IL 104; extraction; separation; CYPHOS IL 104; SOLVENT-EXTRACTION; TRIVALENT LANTHANIDES; BINARY-MIXTURE; ACID; PHOSPHONIUM; CHLORIDE; AMMONIUM; RECOVERY; BEHAVIOR;
D O I
10.1080/08827508.2018.1481058
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Solvent extraction of yttrium(III) from chloride and nitrate solutions were carried out using two bifunctional ionic liquids Cyphos IL 104 and [A336/Cy272]. Comparative study with their constituent extractants showed higher extraction abilities of the ionic liquids for Y(III). The extraction behavior of yttrium using the above ionic liquids was studied as function of different parameters. Ion association neutral complexes were formed in the organic phase. 0.5 M HNO3 could strip 82% and 75.6 % yttrium from the loaded organic phases of 0.01M [A336/Cy272] and Cyphos IL 104, respectively. Separation studies involving binary systems were also investigated.
引用
收藏
页码:46 / 55
页数:10
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