A Desalination Battery

被引:419
作者
Pasta, Mauro [1 ]
Wessells, Colin D. [2 ]
Cui, Yi [2 ,3 ]
La Mantia, Fabio [1 ]
机构
[1] Univ Bochum, Analyt Chem Zentrum Elektrochem, D-44780 Bochum, Germany
[2] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[3] SLAC Natl Accelerator Lab, Stanford Inst Mat & Energy Sci, Menlo Pk, CA 94025 USA
关键词
Seawater desalination; mixing entropy battery; reverse osmosis; ion selectivity; SEAWATER DESALINATION; AQUEOUS-ELECTROLYTE; ENERGY-STORAGE; SODIUM; CARBON; NA4MN9O18; OSMOSIS;
D O I
10.1021/nl203889e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water desalination is an important approach to provide fresh water around the world, although its high energy consumption, and thus high cost, call for new, efficient technology. Here, we demonstrate the novel concept of a "desalination battery", which operates by performing cycles in reverse on our previously reported mixing entropy battery. Rather than generating electricity from salinity differences, as in mixing entropy batteries, desalination batteries use an electrical energy input to extract sodium and chloride ions from seawater and to generate fresh water. The desalination battery is comprised by a Na2-xMn5O10 nanorod positive electrode and Ag/AgCl negative electrode. Here, we demonstrate an energy consumption of 0.29 Wh l(-1) for the removal of 25% salt using this novel desalination battery, which is promising when compared to reverse osmosis (similar to 0.2 Wh l(-1)), the most efficient technique presently available.
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页码:839 / 843
页数:5
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