Surprising magnetic behavior of cobalt(II) ion in recently prepared macrocycle complexes.: Distortion versus intermolecular antiferromagnetic exchange interactions

被引：12
|
作者：
Bayri, A [1 ]
Bahadir, AR
Avcu, FM
Aytekin, Ö
机构：
[1] Inonu Univ, Dept Phys, Arts & Sci Fac, TR-44069 Malatya, Turkey
[2] Inonu Univ, Dept Math, Arts & Sci Fac, TR-44069 Malatya, Turkey
[3] Inonu Univ, Dept Informat, Malatya, Turkey
来源：
TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 08期
关键词：
D O I：
10.1007/s11243-005-6313-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The magnetic moment of the Co2+ stop ion in the newly reported macrocycle complex is analysed for various situations. It is realized that in order to obtain the observed magnetic moment, either some irrelevant parameters or some intermolecular antiferromagnetic interactions must be included in the magnetic Hamiltonian. It is suggested that the complex behaves as a largely distorted octahedron.
引用
收藏
页码：987 / 991
页数：5
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