Synthesis by neutral surfactant assembly of ordered mesoporous organic-inorganic hybrid materials incorporating phosphorus centres

被引：29
作者：
Corriu, RJP [1 ]
Mehdi, A [1 ]
Reyé, C [1 ]
机构：
[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, F-34095 Montpellier 5, France
来源：
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 01期
关键词：
sol-gel; surfactant; phosphine; mesopore;
D O I：
10.1016/S1387-1609(99)80036-X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The co-condensation of tetraethoxysilane (TEOS) and organotrialkoxysilane R'Si(OEt)(3) (R' group containing a phosphorus acorn) in the presence of a neutral surfactant (n-C16H33NH2) template provides ordered mesoporous hybrid materials. We show that further chemical reactions (sulfuration and quaternization) at phosphorus centres do not disrupt. the ordered structure and the textural characteristics of the materials. (C) Academie des sciences/Elsevier, Paris.
引用
收藏
页码：35 / 39
页数：5
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