Polymer globule as a nanoreactor

被引：3

作者：

Kuchanov, S. ^{[1
,2
]}

Pogodin, S. ^{[2
]}

ten Brinke, G. ^{[3
]}

Khokhlov, A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117823, Russia

[2] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, Russia

[3] Univ Groningen, Dept Polymer Chem, NL-9747 AG Groningen, Netherlands

来源：

MACROMOLECULES | 2008年 / 41卷 / 07期

关键词：

D O I：

10.1021/ma702710s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Peculiarities of chemical reactions inside polymer globules with sizes falling in the nanometric range have been theoretically studied. The simplest example of a polymer-catalyzed bimolecular reaction between two low-molecular-weight compounds has been considered to illustrate the advantages of conducting chemical transformations in globular solution of macromolecules. Under theoretical examination of polymer-analogous transformations of polymer molecules, the possibility has been shown of reaction-induced conformational transitions between their coil and globular states. Besides, a pronounced effect has been revealed of the preferential sorption of low-molecular-weight reagents on composition of copolymers formed.

引用

页码：2689 / 2693

页数：5

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