Arene ruthenium bis-saccharinato complexes: Synthesis, molecular structure and catalytic oxidation properties in aqueous solution

被引:15
|
作者
Trieu-Tien Thai [1 ]
Therrien, Bruno [1 ]
Suess-Fink, Georg [1 ]
机构
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
基金
瑞士国家科学基金会;
关键词
Arene; Ruthenium; Saccharinato; Alcohol oxidation; tert-Butyl hydroperoxide; Aqueous solution; TERT-BUTYL HYDROPEROXIDE; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; AEROBIC OXIDATION; SECONDARY ALCOHOLS; ALLYLIC ALCOHOLS; METAL CATALYSIS; MOLYBDENUM; KETONES; ACTIVATION;
D O I
10.1016/j.jorganchem.2011.06.033
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Arene ruthenium complexes [(eta(6)-arene)Ru(sacc)(2)(OH2)] (arene - para-cymeme, benzene) containing an aqua and two saccharinato ligands have been synthesized from [(eta(6)-arene) RuCl2](2) and sodium saccharinate in a water-ethanol mixture (1:1). The aqua complex [(eta(6)-MeC6H4Pri)Ru(sacc)(2)(OH2)] reacts with acetonitrile to give the acetonitrile complex [(eta(6)-MeC6H4Pri)Ru(sacc)(2)(NCMe)]. The corresponding benzene derivative [(eta(6)-C6H6) Ru(sacc)(2)(NCMe)] was obtained from [(eta(6)-C6H6)RuCl2](2) and saccNa in an acetonitrile-methanol mixture (1:1). All new complexes show a piano-stool geometry with two monohapto nitrogen-bonded saccharinato ligands in addition to a H2O or MeCN ligand. All complexes of the type [(eta(6)-arene) Ru(sacc)(2)(OH2)] and [(eta(6)-arene) Ru(sacc)(2)(NCMe)] were found to catalyze the oxidation of secondary alcohols with tert-butyl hydroperoxide ((BuOOH)-O-t) to give the corresponding ketones in aqueous solution. (C) 2011 Elsevier B. V. All rights reserved.
引用
收藏
页码:3285 / 3291
页数:7
相关论文
共 50 条
  • [41] Ruthenium Aqua Complexes Supported by the Klaui Tripodal Ligand: Synthesis, Structure, and Application in Catalytic C-H Oxidation in Water
    So, Yat-Ming
    Wong, Kang-Long
    Sung, Herman H. Y.
    Williams, Ian D.
    Leung, Wa-Hung
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (18) : 2368 - 2374
  • [42] Synthesis, spectroscopy, structure, and reactivity of bis-azapentadienyl-ruthenium-phosphine complexes [1]
    Bleeke, John R.
    Stouffer, Meghan
    Rath, Nigam P.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 781 : 11 - 22
  • [43] Highly water-soluble arene-ruthenium(II) complexes: application to catalytic isomerization of allylic alcohols in aqueous medium
    Lastra-Barreira, Beatriz
    Diez, Josefina
    Crochet, Pascale
    GREEN CHEMISTRY, 2009, 11 (10) : 1681 - 1686
  • [44] Bis(pyrazolyl)acetate and bis(3,5-dimethylpyrazolyl)acetate tris-acetonitrile ruthenium(II) complexes: Synthesis, properties, and structure
    Fields, Alexis E.
    Zurwell, Dane
    Padgett, Clifford W.
    Quillian, Brandon
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 846 : 66 - 73
  • [45] Arene-Ruthenium(II) Complexes with Bioactive ortho-Hydroxydibenzoylmethane Ligands: Synthesis, Structure, and Cytotoxicity
    Pettinari, Riccardo
    Petrini, Agnese
    Marchetti, Fabio
    Pettinari, Claudio
    Riedel, Tina
    Therrien, Bruno
    Dyson, Paul J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (12) : 1800 - 1806
  • [46] Substituent Effects on Physical Properties and Catalytic Activities toward Water Oxidation in Mononuclear Ruthenium Complexes
    Sato, Yoichi
    Takizawa, Shin-ya
    Murata, Shigeru
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (33) : 5495 - 5502
  • [47] Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes
    Eberhard, Jens
    Peuntinger, Katrin
    Froehlich, Roland
    Guldi, Dirk M.
    Mattay, Jochen
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (20-21) : 2682 - 2700
  • [48] Bis(bipyridine)ruthenium(II) complexes with an Aliphatic Sulfinato Donor: Synthesis, Characterization, and Properties
    Tamura, Motoshi
    Tsuge, Kiyoshi
    Igashira-Kamiyama, Asako
    Konno, Takumi
    INORGANIC CHEMISTRY, 2011, 50 (11) : 4764 - 4771
  • [49] Thiolato-Bridged Arene-Ruthenium Complexes: Synthesis, Molecular Structure, Reactivity, and Anticancer Activity of the Dinuclear Complexes [(arene)2Ru2(SR)2Cl2]
    Ibao, Anne-Flore
    Gras, Michael
    Therrien, Bruno
    Suess-Fink, Georg
    Zava, Olivier
    Dyson, Paul J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (09) : 1531 - 1535
  • [50] Organometallic ruthenium(II)-arene complexes with triphenylphosphine amino acid bioconjugates: Synthesis, characterization and biological properties
    Pernar, Margareta
    Kokan, Zoran
    Kralj, Juran
    Glasovac, Zoran
    Tumir, Lidija-Marija
    Piantanida, Ivo
    Eljuga, Domagoj
    Turel, Iztok
    Brozovic, Anamaria
    Kirin, Srecko, I
    BIOORGANIC CHEMISTRY, 2019, 87 : 432 - 446