Study of temperature dependence of saturated vapour pressure of zirconium(IV) beta-diketonates

被引：28
作者：
Morozova, NB
Sysoev, SV
Igumenov, IK
Golubenko, AN
机构：
[1] Institute of Inorganic Chemistry, Novosibirsk
来源：
JOURNAL OF THERMAL ANALYSIS | 1996年 / 46卷 / 05期
关键词：
complexes; zirconium(IV) beta-diketonates;
D O I：
10.1007/BF01979249
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
By means of a tensiometric flow method and a static method with a silica-membrane zero gauge, the dependences of saturated vapour pressure on temperature were obtained for the complexes of zirconium(IV) with acetylacetone, trifluoroacetylacetone, hexafluoroacetylacetone, dipivaloylmethane and pivaloyltrifluoroacetone. The thermodynamic characteristics of the evaporation and sublimation of these complexes were determined.
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页码：1367 / 1373
页数：7
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