Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals

被引：720

作者：

Ruppert, Agnieszka M. ^{[4
]}

Weinberg, Kamil ^{[3
]}

Palkovits, Regina ^{[1
,2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[3] Med Univ Lodz, Dept Pharm & Appl Pharm, PL-90151 Lodz, Poland

[4] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期

关键词：

glycerol; hydrogenolysis; lignocellulose; renewable feedstocks; sorbitol; TRICKLE-BED REACTOR; SUPPORTED RUTHENIUM CATALYST; DILUTE-ACID HYDROLYSIS; CARBON BEARING SO3H; GLUCOSE HYDROGENATION; GLYCEROL HYDROGENOLYSIS; PROPYLENE-GLYCOL; IONIC LIQUID; SELECTIVE HYDROGENATION; BIMETALLIC CATALYSTS;

D O I：

10.1002/anie.201105125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In view of the diminishing oil resources and the ongoing climate change, the use of efficient and environmentally benign technologies for the utilization of renewable resources has become indispensible. Therein, hydrogenolysis reactions offer a promising possibility for future biorefinery concepts. These reactions result in the cleavage of C?C and C?O bonds by hydrogen and allow direct access to valuable platform chemicals already integrated in todays value chains. Thus, hydrogenolysis bears the potential to bridge currently available technologies and future biomass-based refinery concepts. This Review highlights past and present developments in this field, with special emphasis on the direct utilization of cellulosic feedstocks.

引用

页码：2564 / 2601

页数：38

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