Effects of calcination temperatures on photocatalytic activity of SnO2/TiO2 composite films prepared by an EPD method

被引：184

作者：

Zhou, Minghua ^{[1
,2
]}

Yu, Jiaguo ^{[1
]}

Liu, Shengwei ^{[1
]}

Zhai, Pengcheng ^{[1
]}

Jiang, Li ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China

[2] Yunyang Med Coll, Staff Room Chem, Shiyan 442000, Hubei, Peoples R China

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2008年 / 154卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

SnO2/TiO2; composite films; electrophoretic deposition; photocatalytic activity; calcination temperatures;

D O I：

10.1016/j.jhazmat.2007.11.021

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

SnO2/TiO2 composite films were fabricated on transparent electro-conductive glass substrates (F-doped SnO2-coated glass:FrO glass) via an electrophoretic deposition (EPD) method using Degussa P25 as raw materials, and were further characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscope (FESEM), UV-vis diffuse reflectance spectra and Photoluminescence spectra (PL). XRD and XPS results confirmed that the films were composed of TiO2 and SnO2. FESEM images indicated that the as-prepared TiO2 films had roughness surfaces, which consisted of nano-sized particles. The effects of calcination temperatures on the surface morphology, microstructures and photocatalytic activity of SnO2/TiO2 composite films were further investigated. All the prepared SnO2/TiO2 Composite films exhibited high photocatalytic activities for photocatalytic decolorization of Rhodamine-B aqueous solution. At 400 degrees C, the SnO2/TiO2 composite films showed the highest photocatalytic activity due to synergetic effects of low sodium content, good crystallization, appropriate phase composition and slower recombination rate of photogenerated charge carriers. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1141 / 1148

页数：8

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