Photoregulated reversible addition-fragmentation chain transfer (RAFT) polymerization

被引：59

作者：

Li, Shenzhen ^{[1
]}

Han, Guang ^{[2
]}

Zhang, Wangqing ^{[1
,3
]}

机构：

[1] Nankai Univ, Inst Polymer Chem, Coll Chem, Key Lab Funct Polymer Mat,Minist Educ, Tianjin 300071, Peoples R China

[2] Beijing Oriental Yuhong Waterproof Technol Co Ltd, State Key Lab Special Funct Waterproof Mat, Beijing 100123, Peoples R China

[3] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

来源：

POLYMER CHEMISTRY | 2020年 / 11卷 / 11期

基金：

美国国家科学基金会;

关键词：

LIVING RADICAL POLYMERIZATION; PHOTOINDUCED ELECTRON-TRANSFER; COPOLYMER NANO-OBJECTS; ASSEMBLY PHOTO-PISA; MILD VISIBLE-LIGHT; PET-RAFT; DISPERSION POLYMERIZATION; HIGHLY EFFICIENT; FACILE SYNTHESIS; VINYL-ACETATE;

D O I：

10.1039/d0py00054j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The past two decades have witnessed the significant progress of regulated reversible addition-fragmentation chain transfer (RAFT) polymerization, and different strategies, especially those with light, were designed, such as direct photoexcitation of RAFT agents, using photoinitiators and recyclable/degradable photocatalysts. More recently, photosensitive azobenzenes as external photoadditives have also been utilized to switch on/off the RAFT polymerization, in which photoelectron transfer (PET) between free radicals and azobenzenes was involved. This minireview summarizes these recently developed techniques for photoregulated RAFT polymerization and their possible applications.

引用

收藏

页码：1830 / 1844

页数：15

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