B-N versus C-C: How similar are they?

被引:396
作者
Liu, Zhiqiang [1 ]
Marder, Todd B. [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
boron; isoelectronic analogues; nanotubes; nitrogen; polycycles;
D O I
10.1002/anie.200703535
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
One of these bonds is not like the others: Cyclic π systems in which B-N units replace their isoelectronic G-C counterparts have intrigued chemists and materials scientists for decades. The recent report of Piers et al. on the synthesis, crystal structure, and optical properties of 10a-aza-10b-borapyrenes (see picture) represents a major breakthrough in this field. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:242 / 244
页数:3
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