Ferroelectric and piezoelectric properties of SrZrO3-modified Bi0.5Na0.5TiO3 lead-free ceramics

The lead-free SrZrO3-modified Bi0.5Na0.5TiO3 (BNT-SZ100x, with x=0-0.15) ceramics were fabricated by a conventional solid-state reaction method. The effects of SZ addition on BNT ceramics were investigated through X-ray diffraction (XRD), scanning electron microscopy (SEM), ferroelectric and electric field-induced strain characterizations. XRD analysis revealed a pure perovskite phase without any traces of secondary phases. Ferroelectric and bipolar field induced-strain curves indicated a disruption of ferroelectric order upon SZ addition into BNT ceramics. A maximum value of remnant polarization (32 mu C/cm(2)) and piezoelectric constant (102 pC/N) was observed at 5% (mole fraction) of SZ. Maximum value of the electric field-induced strain (S-max=0.24%) corresponding to normalized strain (S-max/E-max=d*(33)=340 pm/V) was obtained at BNT-SZ9.