Porphyrin-based photocatalysts for hydrogen production

被引:43
作者
Wang, Liang [1 ]
Fan, Hongyou [2 ,3 ]
Bai, Feng [1 ]
机构
[1] Henan Univ, Minist Educ, Key Lab Special Funct Mat, Kaifeng, Peoples R China
[2] Univ New Mexico, Sandia Natl Labs, Albuquerque, NM 87131 USA
[3] Univ New Mexico, Dept Chem & Biol Engn, Albuquerque, NM 87131 USA
基金
中国国家自然科学基金;
关键词
EVOLUTION; NANOPARTICLES; GENERATION; CATALYST;
D O I
10.1557/mrs.2019.294
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Photocatalytic hydrogen production from water is a facile and clean approach to convert rich solar energy into chemical fuel. Developing efficient and robust catalysts to accelerate water-splitting speed is key. Porphyrins exist widely in green plants and are a key photosensitizer to absorb and transfer light energy to other parts of the photosynthesis system of plants. They are considered an ideal model to construct artificial photocatalysts for hot-carrier-mediated hydrogen production. This article discusses recent achievements in constructing porphyrin-based photocatalysts for hydrogen production, including porphyrin molecules, self-assembled porphyrins, metal-organic frameworks, conjugated porphyrin polymers, and hybrid nanomaterial-based photocatalysts. The design and synthesis principles, structure-property relationships, as well as urgent issues to be solved in the future for every type of photocatalyst are also discussed.
引用
收藏
页码:49 / 56
页数:8
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