Porous organic polymers as metal free heterogeneous organocatalysts

被引：86

作者：

Debruyne, Maarten ^{[1
]}

Van Speybroeck, Veronique ^{[2
]}

Van Der Voort, Pascal ^{[3
]}

Stevens, Christian V. ^{[1
]}

机构：

[1] Univ Ghent, Dept Green Chem & Technol, Coupure Links 653, B-9000 Ghent, Belgium

[2] Univ Ghent, Dept Chem, Krijgslaan 281 S3, B-9000 Ghent, Belgium

[3] Univ Ghent, Dept Appl Phys, Technol Pk 46, B-9052 Zwijnaarde, Belgium

来源：

GREEN CHEMISTRY | 2021年 / 23卷 / 19期

关键词：

COVALENT TRIAZINE FRAMEWORKS; ONE-POT SYNTHESIS; CONJUGATED MICROPOROUS POLYMERS; CYCLIC CARBONATE SYNTHESIS; SOLID ACID CATALYSTS; FUNCTIONALIZED IONIC LIQUID; HIGHLY EFFICIENT CATALYST; SELECTIVE CO2 SORPTION; KNOEVENAGEL CONDENSATION; CHEMICAL FIXATION;

D O I：

10.1039/d1gc02319e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient catalysis is essential from a green chemistry perspective. Porous organic polymers (POPs) have recently emerged as highly effective materials for catalytic applications. POPs possess controllable compositions and functionalities, high surface areas and can be very stable. In this review we focus on the application of POPs as metal free heterogeneous organocatalysts, a booming field in green chemistry. Acid, base, combined acid-base and hydrogen bonding catalysis are addressed. In addition, chiral catalysis and CO2 utilization with POPs are discussed. The aim is to provide a comprehensive overview of the field, exploring all different types of POPs as metal free catalysts. Special attention is given to the synthesis conditions to provide the reader with more insight into the construction of these types of materials.

引用

页码：7361 / 7434

页数：74

共 347 条

[41] SBA-15 supported triazolium-based ionic liquids as highly efficient and recyclable catalysts for fixation of CO2 with epoxides [J].