Porous organic polymers as metal free heterogeneous organocatalysts

被引：86
作者：
Debruyne, Maarten [1 ]
Van Speybroeck, Veronique [2 ]
Van Der Voort, Pascal [3 ]
Stevens, Christian V. [1 ]
机构：
[1] Univ Ghent, Dept Green Chem & Technol, Coupure Links 653, B-9000 Ghent, Belgium
[2] Univ Ghent, Dept Chem, Krijgslaan 281 S3, B-9000 Ghent, Belgium
[3] Univ Ghent, Dept Appl Phys, Technol Pk 46, B-9052 Zwijnaarde, Belgium
来源：
GREEN CHEMISTRY | 2021年 / 23卷 / 19期
关键词：
COVALENT TRIAZINE FRAMEWORKS; ONE-POT SYNTHESIS; CONJUGATED MICROPOROUS POLYMERS; CYCLIC CARBONATE SYNTHESIS; SOLID ACID CATALYSTS; FUNCTIONALIZED IONIC LIQUID; HIGHLY EFFICIENT CATALYST; SELECTIVE CO2 SORPTION; KNOEVENAGEL CONDENSATION; CHEMICAL FIXATION;
D O I：
10.1039/d1gc02319e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Efficient catalysis is essential from a green chemistry perspective. Porous organic polymers (POPs) have recently emerged as highly effective materials for catalytic applications. POPs possess controllable compositions and functionalities, high surface areas and can be very stable. In this review we focus on the application of POPs as metal free heterogeneous organocatalysts, a booming field in green chemistry. Acid, base, combined acid-base and hydrogen bonding catalysis are addressed. In addition, chiral catalysis and CO2 utilization with POPs are discussed. The aim is to provide a comprehensive overview of the field, exploring all different types of POPs as metal free catalysts. Special attention is given to the synthesis conditions to provide the reader with more insight into the construction of these types of materials.
引用
收藏
页码：7361 / 7434
页数：74
相关论文
共 347 条
[1]   Elucidating the promotional effect of a covalent triazine framework in aerobic oxidation [J].
Abednatanzi, Sara ;
Derakhshandeh, Parviz Gohari ;
Tack, Pieter ;
Muniz-Miranda, Francesco ;
Liu, Ying-Ya ;
Everaert, Jonas ;
Meledina, Maria ;
Vanden Bussche, Flore ;
Vincze, Laszlo ;
Stevens, Christian, V ;
Van Speybroeck, Veronique ;
Vrielinck, Henk ;
Callens, Freddy ;
Leus, Karen ;
Van Der Voort, Pascal .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 269
[2]   Metal-free activation of molecular oxygen by covalent triazine frameworks for selective aerobic oxidation [J].
Abednatanzi, Sara ;
Derakhshandeh, Parviz Gohari ;
Leus, Karen ;
Vrielinck, Henk ;
Callens, Freddy ;
Schmidt, Johannes ;
Savateev, Aleksandr ;
Van der Voort, Pascal .
SCIENCE ADVANCES, 2020, 6 (14)
[3]  
Abrouki Y., 2013, AM J BIOL CHEM PHARM, V1, P28
[4]   Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review [J].
Agarwal, Bhumica ;
Kailasam, Kamalakannan ;
Sangwan, Rajender Singh ;
Elumalai, Sasikumar .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2018, 82 :2408-2425
[5]   Synthesis and high-throughput testing of multilayered supported ionic liquid catalysts for the conversion of CO2 and epoxides into cyclic carbonates [J].
Agrigento, Paola ;
Al-Amsyar, Syed M. ;
Soree, Benjamin ;
Taherimehr, Masoumeh ;
Gruttadauria, Michelangelo ;
Aprile, Carmela ;
Pescarmona, Paolo P. .
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) :1598-1607
[6]   Lower Activation Energy for Catalytic Reactions through Host-Guest Cooperation within Metal-Organic Frameworks [J].
Aguila, Briana ;
Sun, Qi ;
Wang, Xiaoliang ;
O'Rourke, Erica ;
Al-Enizi, Abdullah M. ;
Nafady, Ayman ;
Ma, Shengqian .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (32) :10107-10111
[7]   New strategies for organic catalysis: The first highly enantioselective organocatalytic Diels-Alder reaction [J].
Ahrendt, KA ;
Borths, CJ ;
MacMillan, DWC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (17) :4243-4244
[8]   A Tailored Microenvironment for Catalytic Biomass Conversion in Inorganic-Organic Nanoreactors [J].
Alamillo, Ricardo ;
Crisci, Anthony J. ;
Gallo, Jean Marcel R. ;
Scott, Susannah L. ;
Dumesic, James A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (39) :10349-10351
[9]   Chiral catalysts immobilized on achiral polymers: effect of the polymer support on the performance of the catalyst [J].
Altava, Belen ;
Isabel Burguete, M. ;
Garcia-Verdugo, Eduardo ;
Luis, Santiago V. .
CHEMICAL SOCIETY REVIEWS, 2018, 47 (08) :2722-2771
[10]   Insights into the Asymmetric Heterogeneous Catalysis in Porous Organic Polymers: Constructing A TADDOL-Embedded Chiral Catalyst for Studying the Structure-Activity Relationship [J].
An, Wan-Kai ;
Han, Man-Yi ;
Wang, Chang-An ;
Yu, Si-Min ;
Zhang, Yuan ;
Bai, Shi ;
Wang, Wei .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (35) :11019-11028
12345678910