Advances with supercritical fluids [review]

被引:117
作者
Hauthal, WH [1 ]
机构
[1] Univ Leipzig, Wilhelm Ostwald Inst Phys & Theoret Chem, D-04103 Leipzig, Germany
关键词
sustainable chemistry; supercritical fluids; fluid phase equilibria; phenomenology; solvatochromism; models; equations of state; chemical engineering data; supercritical fluid extraction; chemical syntheses and reactions; materials processing; dyeing; review;
D O I
10.1016/S0045-6535(00)00332-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the last decade, supercritical fluids more and more have been proved as environmentally benign media for chemical and related processes. Many new processes and products have been developed, using the inherent physical and chemical properties of supercritical fluids. Moreover, these processes also promise economic effects. The prerequisites for this success however, are a sound knowledge of physico-chemical properties of- and phenomena in - supercritical mixtures and the availability of other chemical engineering data. This requires an effective exchange of knowledge between a large number of branches of science. In the following, a lot of recent papers will be cited, which should give an overview of actual results on Fundamentals and their applications. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:123 / 135
页数:13
相关论文
共 191 条
[1]  
AALTO MA, 1999, EQUIL, V166, P183
[2]   Catalytic hydrodesulfurization of dibenzothiophene through partial oxidation and a water-gas shift reaction in supercritical water [J].
Adschiri, T ;
Shibata, R ;
Sato, T ;
Watanabe, M ;
Arai, K .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (07) :2634-2638
[3]   Mutual diffusion coefficients of benzene in supercritical carbon dioxide [J].
Ago, K ;
Nishiumi, H .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1999, 32 (05) :563-568
[4]   Solubility of individual polychlorinated biphenyl (PCB) congeners in supercritical fluids:: CO2, CO2/MeOH and CO2/n-C4H10 [J].
Anitescu, G ;
Tavlarides, LL .
JOURNAL OF SUPERCRITICAL FLUIDS, 1999, 14 (03) :197-211
[5]  
[Anonymous], 1999, ANGEW CHEM-GER EDIT
[6]   Solubility determination of TNT and wax and their fractionation from an explosive material using a supercritical fluid [J].
Ashraf-Khorassani, M ;
Taylor, LT .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (06) :1254-1258
[7]   The dyeing of polyolefin fibers in supercritical carbon dioxide part II: The influence of dye structure on the dyeing of fabrics and on fastness properties [J].
Bach, E ;
Cleve, E ;
Schollmeyer, E .
JOURNAL OF THE TEXTILE INSTITUTE, 1998, 89 (04) :657-668
[8]  
BACH E, 1999, MELLIAND INT, V2, P165
[9]  
BACH E, 1999, UNPUB J SOC DYERS CO
[10]  
BACH E, 1998, P 5 M SUP FLUIDS MAT, V1