Base metal alloys with self-healing native conductive oxides for electrical contact materials

被引:13
作者
Aindow, M. [1 ,2 ]
Alpay, S. P. [1 ,2 ]
Liu, Y. [1 ,2 ]
Mantese, J. V. [3 ]
Senturk, B. S. [1 ,2 ]
机构
[1] Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA
[2] Univ Connecticut, Dept Chem Mat & Biomol Engn, Storrs, CT 06269 USA
[3] United Technol Res Ctr, E Hartford, CT 06108 USA
关键词
D O I
10.1063/1.3499369
中图分类号
O59 [应用物理学];
学科分类号
摘要
Base metals for electrical contacts exhibit high bulk conductivities but form low-conductivity native oxide scales in air, leading to unacceptably high contact resistances. Here we show that alloying base metals can lead to higher conductivity native scales by: doping to enhance carrier concentration; inducing mixed oxidation states to give electron/polaron hopping; and/or phase separation for conducting pathways. Data from Cu-La, Fe-V, and Ni-Ru alloys demonstrate the viability of these approaches, yielding contact resistances up to 10(6) times lower than that for oxidized Cu. (c) 2010 American Institute of Physics. [doi:10.1063/1.3499369]
引用
收藏
页数:3
相关论文
共 10 条
[1]   ELECTRICAL EFFECTS OF FRETTING CONNECTOR CONTACT MATERIALS - A REVIEW [J].
ANTLER, M .
WEAR, 1985, 106 (1-3) :5-33
[2]  
*ASTM, B66797 ASTM
[3]  
Gaskell D.R., 2003, Introduction to the Thermodynamics of Materials, V4th
[4]   Metal-insulator transitions [J].
Imada, M ;
Fujimori, A ;
Tokura, Y .
REVIEWS OF MODERN PHYSICS, 1998, 70 (04) :1039-1263
[5]   Magnetic, transport, and optical properties of monolayer copper oxides [J].
Kastner, MA ;
Birgeneau, RJ ;
Shirane, G ;
Endoh, Y .
REVIEWS OF MODERN PHYSICS, 1998, 70 (03) :897-928
[6]   ELECTRONIC-STRUCTURE OF RUO-2, OSO-2, AND IRO-2 [J].
MATTHEISS, LF .
PHYSICAL REVIEW B, 1976, 13 (06) :2433-2450
[7]  
Tamai T., 1989, Electronics and Communications in Japan, Part 2 (Electronics), V72, P87, DOI 10.1002/ecjb.4420720710
[8]  
Timsit RS, 1998, ELECTRICAL CONTACTS - 1998, P1, DOI 10.1109/HOLM.1998.722422
[9]  
Tsuda N., 2000, Electronic Conduction in Oxides
[10]  
ACER NIST PHASE EQUI