Synthesis and use of a stable aminal derived from TsDPEN in asymmetric organocatalysis

被引：14
作者：
Gosiewska, Silvia [1 ]
Soni, Rina [1 ]
Clarkson, Guy J. [1 ]
Wills, Martin [1 ]
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 32期
基金：
英国工程与自然科学研究理事会;
关键词：
MICHAEL REACTION; ALPHA-AMINATION; ALDEHYDES; KETONES; CATALYSIS;
D O I：
10.1016/j.tetlet.2010.06.017
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A stable aminal formed stereoselectively from (R,R)-N-tosyl-1,2-diphenyl-1,2-ethylenediamine (TsDPEN) is capable of asymmetric organocatalysis of Diels-Alder and alpha-amination reactions of aldehydes. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4214 / 4217
页数：4
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