An innovation: Dendrite free quinone paired with ZnMn2O4 for zinc ion storage

被引：104

作者：

Yan, Lijing ^{[1
]}

Zeng, Xiaomin ^{[1
]}

Li, Zeheng ^{[1
]}

Meng, Xiangjuan ^{[1
]}

Wei, Di ^{[1
]}

Liu, Tiefeng ^{[2
]}

Ling, Min ^{[1
]}

Lin, Zhan ^{[2
]}

Liang, Chengdu ^{[1
]}

机构：

[1] Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Manufacture T, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China

[2] Guangdong Univ Technol, Coll Light Ind & Chem Engn, Guangzhou 510006, Peoples R China

来源：

MATERIALS TODAY ENERGY | 2019年 / 13卷

关键词：

Aqueous zinc-ion batteries; ZnMn2O4; cathode; Organic quinone anode; Dendrite free; Stationary energy storage; CYCLE LIFE; ELECTRODE MATERIALS; LITHIUM; ANODE; BATTERIES; CAPACITY; MECHANISM; DISCHARGE; SULFATE; GROWTH;

D O I：

10.1016/j.mtener.2019.06.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphite was reported by J.O. Besenhard as the reservoir for alkali ions in 1974. The booming period of lithium-ion batteries arrived after the graphite patent issued by Sony Co. in 1991. The flourish development is due to the address of lithium dendrite issue through the substitution from lithium metal to graphite. Currently, the zinc dendrite formation in zinc-ion batteries is one of the major issues. Herein, we fabricate a zinc-ion full battery by replacing zinc metal with organic quinone, which is a zinc dendrite free material. This novel zinc-ion full battery exhibits excellent cycling stability with capacity retention of 94.4% and high specific capacity of 189.5 mA h g(-1) after 500 cycles. Ascribed to the low cost of quinone and long cycle performance, this work could inaugurate a new era for rechargeable aqueous zinc-ion batteries. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：323 / 330

页数：8

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