Multiscale dynamics of 1H and 19F in confined ionogels for lithium batteries

被引：22

作者：

Petit, Dominique ^{[1
]}

Korb, Jean-Pierre ^{[1
]}

Levitz, Pierre ^{[1
]}

LeBideau, Jean ^{[2
]}

Brevet, David ^{[3
]}

机构：

[1] Ecole Polytech, CNRS, F-91128 Palaiseau, France

[2] Univ Nantes, Inst Mat Jean Rouxel IMN, CNRS, UMR 6502, Nantes, France

[3] Univ Montpellier 2, Inst Charles Gerhardt, F-34095 Montpellier, France

来源：

COMPTES RENDUS CHIMIE | 2010年 / 13卷 / 04期

关键词：

Ionic liquids; Lithium batteries; Longitudinal nuclear relaxation; Field cycling relaxometry; Confinement; NMR RELAXOMETRY; IONIC LIQUIDS; FLUID;

D O I：

10.1016/j.crci.2009.08.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present the first results of the nuclear magnetic relaxation dispersion (NMRD) of the confined proton-bearing cation (BMI) and fluorine-bearing anion (TFSI) pair of ionic liquids (Li+-ionogels) confined within a silica-like mesoporous matrices designed for lithium batteries. These results are in favour of a very-correlated dynamical motion of the anion-cation pair within the solid and disordered silica matrix. (C) 2009 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

引用

页码：409 / 411

页数：3

共 9 条

[1] Mixed ionic liquid as electrolyte for lithium batteries [J].