The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre

被引：3
作者：
Humbert, Nicolas [1 ]
Mazet, Clement [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, 30 Quai Ernest Ansermet, CH-1211 Geneva, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 70期
基金：
瑞士国家科学基金会;
关键词：
PRIMARY ALLYLIC ALCOHOLS; CATALYZED ASYMMETRIC ISOMERIZATION; WERNERS COORDINATION CHEMISTRY; H BOND ACTIVATION; TERMINAL EPOXIDES; VISIBLE-LIGHT; LIGANDS; CHIRALITY; METATHESIS; MOP;
D O I：
10.1039/c6cc06020j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report herein the highly diastereoselective synthesis of octahedral cationic Ir(III) hydride complexes with a stereogenic metal centre following various strategies. The configurational stability of these compounds has also been investigated.
引用
收藏
页码：10629 / 10631
页数：3
相关论文
共 55 条
  • [1] Chiral-at-metal complexes and their catalytic applications in organic synthesis
    Bauer, Eike B.
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (08) : 3153 - 3167
  • [2] BRUNNER H, 1999, ANGEW CHEM, V111, P1248
  • [3] SPECIFICATION OF MOLECULAR CHIRALITY
    CAHN, RS
    INGOLD, C
    PRELOG, V
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1966, 5 (04) : 385 - &
  • [4] Chiral-at-metal octahedral ruthenium(II) complexes with achiral ligands:: A new type of enantioselective catalyst
    Chavarot, M
    Ménage, S
    Hamelin, O
    Charnay, F
    Pécaut, J
    Fontecave, M
    [J]. INORGANIC CHEMISTRY, 2003, 42 (16) : 4810 - 4816
  • [5] Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation
    Colby, Denise A.
    Bergman, Robert G.
    Ellman, Jonathan A.
    [J]. CHEMICAL REVIEWS, 2010, 110 (02) : 624 - 655
  • [6] Connelly N. G., 2005, NOMENCLATURE INORGAN
  • [7] Constant S., 2005, CHEM COMMUN, V250
  • [8] Transfer of chirality from ligands to metal centers: recent examples
    Crassous, Jeanne
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (78) : 9684 - 9692
  • [9] Chiral olefins as steering ligands in asymmetric catalysis
    Defieber, Christian
    Gruetzmacher, Hansjoerg
    Carreira, Erick M.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (24) : 4482 - 4502
  • [10] Metal complexes as structural templates for targeting proteins
    Doerr, Markus
    Meggers, Eric
    [J]. CURRENT OPINION IN CHEMICAL BIOLOGY, 2014, 19 : 76 - 81
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