Electrochemistry and liquid crystal properties of mono-substituted 1,2,3-triazolylferrocene derivatives

被引：11
作者：
Zhao, Haiying [1 ]
Liu, Xiaoyin [1 ]
Chuo, Luopeng [1 ]
Chen, Shufeng [1 ]
Bian, Zhanxi [1 ]
机构：
[1] Inner Mongolia Univ, Coll Chem & Chem Engn, Inner Mongolia Key Lab Fine Organ Synth, Hohhot 010021, Peoples R China
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2015年 / 206卷
基金：
中国国家自然科学基金;
关键词：
Ferrocene; 1,2,3-Triazole; Electrochemistry; Liquid crystal; 1,2,3-(NH)-TRIAZOLYLFERROCENE DERIVATIVES; CLICK CHEMISTRY; FERROCENE; COLUMNAR; COMPLEXES; COPPER(II); BEHAVIOR; PHASE; UNIT;
D O I：
10.1016/j.molliq.2015.02.031
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Mono-substituted 1,2,3-triazolylferrocene derivatives with nitro groups (2a-2c) had been synthesized and characterized. The UV-vis absorption spectra of these compounds corresponded to the assembled spectra of ferrocene and aryl substitute groups in comparison with the control compound 2d without a ferrocenyl, and the fluorescence spectra showed a maximum at about 380 nm in CH2Cl2. The cyclic voltammograms of 2a-2c showed the quasi-reversible oxidation waves of the ferrocenyl groups, and these waves anodically shifted in comparison with the ferrocene standard due to the electron withdrawing effect of the 1,2,3-triazole ring and nitro groups. According to thermal polarizing microscopy, differential scanning calorimetry and powder X-ray diffraction studies, compounds 2a-2d were all non-mesomorphic and displayed crystal polymorphic phase transitions upon heating. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：213 / 217
页数：5
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