Green Synthesis of a Bio-Based Epoxy Curing Agent from Isosorbide in Aqueous Condition and Shape Memory Properties Investigation of the Cured Resin

被引：45

作者：

Li, Chao ^{[1
]}

Dai, Jinyue ^{[1
]}

Liu, Xiaoqing ^{[1
]}

Jiang, Yanhua ^{[1
]}

Ma, Songqi ^{[1
]}

Zhu, Jin ^{[1
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2016年 / 217卷 / 13期

基金：

中国国家自然科学基金;

关键词：

bio-based epoxy; isosorbide; shape memory polymer; thiol-ene reaction; EPOXIDIZED LINSEED OIL; IMPACT PROPERTIES; DIGLYCIDYL ETHER; BISPHENOL-A; SOYBEAN-OIL; ACID; THERMO; ANHYDRIDE; POLYMER;

D O I：

10.1002/macp.201600055

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The bio-based diamine and epoxy monomer derived from isosorbide are synthesized. Especially, the diamine is obtained using microwave assistant thiol-ene coupling reaction in the aqueous media and the influence of reaction parameters, such as initiator content and reaction time, are investigated. After curing the synthesized epoxy monomer together with the diamine, properties of the cured resins are studied by differential sscanning calorimetry, dynamic mechanical analysis, and thermogravimetric analyzer. Results demonstrate that the cured resin has good shape fixity, good shape recovery, and satisfied thermal stability despite the presence of heteroatoms. This bio-based epoxy resin shows great potential to be used as a candidate for shape memory material. Considering the bio-based feedstock and environmental friendly synthetic process, a "green + green" strategy to prepare thermosetting resins with advanced properties is provided in this paper.

引用

页码：1439 / 1447

页数：9

共 39 条

[21] Novel bio-based flexible epoxy resin from diglycidyl ether of bisphenol A cured with castor oil maleate [J].

Rosu, D. ;

Mustata, F. ;

Tudorachi, N. ;

Musteata, V. E. ;

Rosu, L. ;

Varganici, C. D. .

RSC ADVANCES, 2015, 5 (57) :45679-45687

[22] Network structure and properties of crosslinked bio-based epoxy resin composite: An in-silico multiscale strategy with dynamic curing reaction process [J].

Wang, Yan ;

Gan, Han-Lin ;

Liang, Chi-Xin ;

Zhang, Zhong-Yan ;

Xie, Mo ;

Xing, Ji-Yuan ;

Xue, Yao-Hong ;

Liu, Hong .

GIANT, 2021, 7

[23] An investigation of novel biodegradable flexible copolyester derived from bio-based isosorbide: Synthesis and characterization of poly (butylene-co-isosorbide sebacate) [J].

Jang, Hyunho ;

Park, Su -il .

MATERIALS TODAY SUSTAINABILITY, 2024, 26

[24] Synthesis and characterization of polyurethane rigid foams from polyether polyols with isosorbide as the bio-based starting agent [J].

Jiang, Ting ;

Wang, Wenjuan ;

Yu, Dinghua ;

Huang, Di ;

Wei, Na ;

Hu, Yi ;

Huang, He .

JOURNAL OF POLYMER RESEARCH, 2018, 25 (06)

[25] Synthesis and characterization of polyurethane rigid foams from polyether polyols with isosorbide as the bio-based starting agent [J].

Ting Jiang ;

Wenjuan Wang ;

Dinghua Yu ;

Di Huang ;

Na Wei ;

Yi Hu ;

He Huang .

Journal of Polymer Research, 2018, 25

[26] Highly pure curing agent from tomato waste for bio-based anti-corrosion epoxy coatings [J].

Suriano, Raffaella ;

Magni, Mirko ;

Tagliabue, Beatrice ;

Re, Valentina ;

Ciapponi, Riccardo ;

Nasti, Rita ;

Cavallaro, Marco ;

Beretta, Giangiacomo ;

Turri, Stefano ;

Levi, Marinella .

EUROPEAN POLYMER JOURNAL, 2025, 223

[27] Preparation and properties of novel bio-based epoxy resin thermosets from lignin oligomers and cardanol [J].

Liu, Guifeng ;

Jin, Can ;

Huo, Shuping ;

Kong, Zhenwu ;

Chu, Fuxiang .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2021, 193 :1400-1408

[28] Bio-based trifunctional diphenolic acid epoxy resin with high Tg and low expansion coefficient: synthesis and properties [J].

Wei, Junji ;

Duan, Yajun ;

Wang, Hao ;

Hui, Jizhuang ;

Qi, Jiamin .

POLYMER BULLETIN, 2023, 80 (09) :10457-10471

[29] A novel efficient flame-retardant curing agent for epoxy resin based on P-N synergistic effect: Bio-based benzoxazine phosphate ester [J].

Zhou, Xuan ;

Li, Rongzhi ;

Fu, Fei ;

Shen, Minggui ;

Li, Qiaoguang ;

Liu, He ;

Xu, Xu ;

Song, Zhanqian .

CHEMICAL ENGINEERING JOURNAL, 2024, 499

[30] One-pot synthesis of bio-based polycarbonates from dimethyl carbonate and isosorbide under metal-free condition [J].

Fang, Wenjuan ;

Zhang, Zhencai ;

Yang, Zifeng ;

Zhang, Yaqin ;

Xu, Fei ;

Li, Chenhao ;

An, Hongzhe ;

Song, Ting ;

Luo, Yunjun ;

Zhang, Suojiang .

GREEN CHEMISTRY, 2020, 22 (14) :4550-4560

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