Arenediazonium salts as electrophiles for the oxidative addition of gold(I)

被引：50

作者：

Omar Asomoza-Solis, Eric ^{[1
]}

Rojas-Ocampo, Jonathan ^{[1
]}

Alfredo Toscano, Ruben ^{[1
]}

Porcel, Susana ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Circuito Exterior S-N,Ciudad Univ, Mexico City 04510, DF, Mexico

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 45期

关键词：

TRIVALENT PHOSPHORUS-COMPOUNDS; REDUCTIVE ELIMINATION; COUPLING REACTIVITY; ARYLBORONIC ACIDS; DIAZONIUM SALTS; ARYL HALIDES; CATALYSIS; ALKENES; COMPLEXES; PHOTOREDOX;

D O I：

10.1039/c6cc03105f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arenediazonium salts generated in situ fromanilines have been found for the first time to efficiently oxidize [AuCl(L)] (L = SMe2, PPh3) complexes in DMSO as a solvent, under thermal conditions. The structure of the [AuArCl2(L)] complexes formed has been confirmed by X ray diffraction analyses. These complexes have been used as intermediates, in a one pot cross-coupling reaction of anilines with silver acetylides.

引用

页码：7295 / 7298

页数：4

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