Glass transition thermodynamics of organic nanoparticles

被引：32

作者：

Zhang, Z ^{[1
]}

Zhao, M ^{[1
]}

Jiang, Q ^{[1
]}

机构：

[1] Jilin Univ Technol, Dept Mat Sci & Engn, Changchun 130025, Peoples R China

来源：

PHYSICA B | 2001年 / 293卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

glass transition; heat capacity; glass; organic nanoparticles;

D O I：

10.1016/S0921-4526(00)00564-0

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Finite size effects of organic particles on glass transition temperature and heat capacity difference of glass and liquid at glass transition temperature are considered by our phenomenological model. As size of the organic particle decreases, its glass transition temperature and heat capacity difference decrease. However, this size effect is much weaker than that of the melting transition. The model predictions are in agreement with available experimental results of o-terphenyl and benzyl alcohol nanoparticles. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：232 / 236

页数：5

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