Dynamic Changes in Dimensional Structures of Co-Complex Crystals

被引：33

作者：

Kondo, Atsushi ^{[2
,3
]}

Nakagawa, Tomohiro ^{[2
]}

Kajiro, Hiroshi ^{[1
]}

Chinen, Ayako ^{[2
]}

Hattori, Yoshiyuki ^{[4
]}

Okino, Fujio ^{[4
]}

Ohba, Tomonori ^{[2
]}

Kaneko, Katsumi ^{[2
]}

Kanoh, Hirofumi ^{[2
]}

机构：

[1] Nippon Steel Corp Ltd, Chiba 2938511, Japan

[2] Chiba Univ, Grad Sch Sci, Inage Ku, Chiba 2638522, Japan

[3] Shinshu Univ, Collaborat Innovat Ctr Nanotech FIBER nanoFIC, Ueda Nagano 3868567, Japan

[4] Shinshu Univ, Fac Text Sci & Technol, Dept Chem, Ueda, Nagano 3868567, Japan

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 20期

关键词：

METAL-ORGANIC FRAMEWORK; POROUS COORDINATION POLYMER; CLATHRATE-FORMATION; HYDROGEN STORAGE; BUILDING-BLOCKS; SINGLE-CRYSTAL; NETWORK; ADSORPTION; DESIGN; MOF;

D O I：

10.1021/ic100753g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A two-dimensional flexible porous coordination polymer (2D-PCP) that shows expansion/shrinkage structural transformation accompanied by molecular accommodation was synthesized by control of dimensionality in zero-dimensional and one-dimensional PCPs. The dynamic structural transformation cooperatively proceeds in the solid state with a drastic molecular rearrangement Kinetics of the structural transformation was investigated

引用

页码：9247 / 9252

页数：6

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