Structure and electrochemical characteristics of Ti0.10Zr0.15V0.35Cr0.10Ni0.30-LaNi4Al0.4Mn0.3Co0.3 composite hydrogen storage alloy

被引：4
作者：
Wang, Yanzhi [1 ,2 ]
Zhao, Minshou [1 ,2 ]
机构：
[1] Yanshan Univ, Coll Environm & Chem Engn, Qinhuangdao 066004, Peoples R China
[2] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2010年 / 35卷 / 15期
关键词：
V-based solid solution; Composite alloy; Hydrogen storage alloy; Electrochemical characteristics; Ni/MH battery; METAL HYDRIDE ELECTRODES; SOLID-SOLUTION ALLOYS; PHASE STRUCTURES; DETERIORATION BEHAVIOR; TI; CR; MICROSTRUCTURE; PERFORMANCES; SUBSTITUTION; ELEMENTS;
D O I：
10.1016/j.ijhydene.2009.12.019
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Structure and electrochemical characteristics of Ti0.10Zr0.15V0.35Cr0.10Ni0.30 (matrix alloy) - 1 mass% LaNi4Al0.4Mn0.3Co0.3 composite hydrogen storage alloy have been investigated systematically. The main phase of composite alloy is composed of V-based solid solution phase with a BCC structure and C14 Laves phase with hexagonal structure, while secondary phase which has a composition close to Zr (Ti, V, Ni, Cr, Al, Co, La)(1.8) also exists in the composite alloy. The real maximum discharge capacity of the composite alloy electrode is 354.9 mAh g(-1), and distinct synergetic effect appears during composite process. Comparing with the matrix alloy, the thermodynamic performances, electrochemical characteristics, dynamic performances for the composite alloy electrode have been improved. The secondary phase is probably responsible for the improvement of electrochemical characteristics of the matrix alloy. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：8268 / 8274
页数：7
相关论文
共 50 条
[21]   Experimental investigation of the hydrogen storage capacity in LaNi3.6Al0.4Mn0.3Co0.7 alloy [J].
Harrat, Safia ;
Briki, Chaker ;
Sahli, Mounir ;
Settar, Abdelhakim ;
Chetehouna, Khaled ;
Jemni, Abdelmajid .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 77 :33-39
[22]   Effects of Boron Addition on Microstructures and Electrochemical Properties of (Ti0.65Zr0.30)1.10(V0.5Mn0.3Cr0.4Ni0.8)Bx Hydrogen Storage Alloys [J].
Pan Chongchao ;
Liu Xiaofang ;
Yu Ronghai .
RARE METAL MATERIALS AND ENGINEERING, 2010, 39 (11) :2023-2026
[23]   Experimental study of the influences substitution from Ni by Co, Al and Mn on the hydrogen storage properties of LaNi3.6Mn0.3Al0.4Co0.7 alloy [J].
Briki, Chaker ;
Belkhiria, Sihem ;
Dhaou, Mohamed Houcine ;
de Rango, Patricia ;
Jemni, Abdelmajid .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (15) :10081-10088
[24]   The phase structure and electrochemical properties of the melt-spun alloy Zr0.7Ti0.3Mn0.4V0.4Ni1.2 [J].
Zhang, SK ;
Wang, QD ;
Lei, YQ ;
Lü, GL ;
Chen, LX ;
Wu, F .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 330 :855-860
[25]   Microstructures and electrochemical characteristics of Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3 hydrogen storage alloys prepared by mechanical alloying [J].
Tian, Xiao ;
Liu, Xiang-dong ;
Xu, Jin ;
Feng, Hong-wei ;
Chi, Bo ;
Huang, Li-Hong ;
Yan, Su-Fang .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (05) :2295-2302
[26]   Phase structure and electrochemical properties of non-stoichiometric La0.7Ce0.3(Ni3.65Cu0.75Mn0.35Al0.15(Fe0.43B0.57)0.10)x hydrogen storage alloys [J].
Fan Yanping ;
Liu Baozhong ;
Zhang Baoqing ;
Ji Liqiang ;
Zhang Zhi .
JOURNAL OF RARE EARTHS, 2012, 30 (12) :1249-1254
[27]   Crystal structural and electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30-xMnx (x=0-0.12) alloys [J].
Chai, Y. J. ;
Zhao, M. S. ;
Wang, N. .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2008, 147 (01) :47-51
[28]   Effects of Rapid Quenching on Electrochemical Properties of MlNi3.55Co0.75Mn0.4Al0.3/5wt% Mg2Ni Composite Hydrogen Storage Alloy [J].
Tian Xiao ;
Tegus O ;
Hai Shan ;
Yao Zhan-Quan .
JOURNAL OF INORGANIC MATERIALS, 2012, 27 (11) :1179-1184
[29]   Microstructure and electrochemical characteristics of La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-x(V0.81Fe0.19)x hydrogen storage alloys [J].
Liu Baozhong ;
Hu Mengjuan ;
Li Anming ;
Ji Liqiang ;
Zhang Baoqing ;
Zhu Xilin .
JOURNAL OF RARE EARTHS, 2012, 30 (08) :769-774
[30]   Microstructure and electrochemical characteristics of Ti0.17Zr0.08V0.34Nb0.01Cr0.1Ni0.3 hydride alloy [J].
Qiao, YQ ;
Zhao, MS ;
Li, MY ;
Zhu, XJ ;
Cao, GY .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (03) :415-420
12345