Novel Lithium-Ion Capacitor Based on a NiO-rGO Composite

被引:4
作者
An, Qi [1 ]
Zhao, Xingru [2 ]
Suo, Shuangfu [1 ]
Bai, Yuzhu [1 ]
机构
[1] Tsinghua Univ, Dept Mech Engn, Beijing 100084, Peoples R China
[2] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 101400, Peoples R China
关键词
lithium-ion capacitors; NiO-rGO composite; energy density; power density; HOLLOW SPHERES; GRAPHENE COMPOSITE; STORAGE; ENERGY; ANODE; SHELL; NANOLAYER; HYDROGEL; DESIGN; OXIDE;
D O I
10.3390/ma14133586
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g(-1) and a charge capacity of 945.8 mA h g(-1)) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg(-1)), a high power density (10.94 kW kg(-1)), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.
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页数:11
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