Synthesis and characterization of mononuclear and tetranuclear palladium(II) complexes with 2-(phenylmethyleneamino)benzenethiolate

被引：10

作者：

Kawamoto, T ^{[1
]}

Nagasawa, I ^{[1
]}

Kushi, Y ^{[1
]}

Konno, T ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

INORGANICA CHIMICA ACTA | 2003年 / 348卷

关键词：

palladium(II) complexes; C; N; S-ligand complexes; crystal structures; metal-ligand interaction;

D O I：

10.1016/S0020-1693(02)01474-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two palladium(II) complexes, [Pd(Hphbt-N.S)(2)] (1; Hphbt=2-(phenylmethyleneamino)benzenethiolate) and [Pd-4(phbt-C,N,S)4] (2), were newly prepared. X-ray and H-1 NMR studies indicated the presence of (PdH)-H-...-C interaction in the mononuclear 1, which is assumed to play an important role in the cyclometalation reaction leading to the tetranuclear structure in 2. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：217 / 220

页数：4

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