A new 3-fold interpenetrated metal-organic framework (MOF) based on trinuclear zinc(II) clusters as secondary building unit (SBU)

被引：39

作者：

Liu, Yong-Liang

Yue, Ke-Fen ^{[1
]}

Shan, Bing-Hui

Xu, Li-Li

Wang, Cheng-Jun

Wang, Yao-Yu

机构：

[1] Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian, Shaanxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 17卷

关键词：

Metal-organic framework (MOF); The secondary building unit (SBU); Interpenetration; COORDINATION POLYMERS; ADSORPTION PROPERTIES; HYDROGEN ADSORPTION; LIGANDS; NETWORKS; BLOCKS; DESIGN;

D O I：

10.1016/j.inoche.2011.12.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metal-organic framework (MOF), [Zn-3(4,4'-ADB)(3)(BIB)(2)](n) (1) has been synthesized based on mixed bridging ligands BIB and 4,4'-ADB (BIB = 1,4-bis(2-methyl-imidazol-1-yl) butane, 4,4'-ADB = azobenzene-4,4'-dicarboxylica acid). This MOF is a 3D structure with trinuclear zinc(II) clusters as SBU. The trinuclear zinc (II) clusters of line style feature zincs in two tetrahedral and one octahedral coordination environments. The MOF exhibits a 3-fold interpenetrated framework with 3(6).4(18).5(3).6 topology, which reduces the effective void but stabilizes the compound. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：30 / 33

页数：4

共 33 条

[1] Coordination chemistry of N,N,4-tris(pyridin-2-ylmethyl)aniline:: a novel flexible, multimodal ligand [J].