Studies of the equilibria of complexes of Pr(III), Nd(III), Eu(III), Gd(III), Dy(III) and Er(III) with quercetin-5′-sulfonic acid in aqueous solutions

被引:0
作者
Kopacz, M [1 ]
Bujonek, B [1 ]
Nowak, D [1 ]
Kopacz, S [1 ]
机构
[1] Univ Technol, Fac Chem, Dept Inorgan & Analyt Chem, PL-35959 Rzeszow, Poland
关键词
quercetin-5 '-sulfonic acid; complexes; concentration stability constants; conditional stability constants; spectrophotometry; potentiometry;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The equilibria Of the dissociation reaction of QSA as well as those of the complexation of QSA with Pr(III), Nd(III), Eu(III), Gd(III), Dy(III) and Er(III) in aqueous solutions were investigated. The composition and formation constants of the complexes were determined by the spectrophotometric and potentiometric methods. The spectrophotometric method was suggested to determine the above lanthanides with QSA.
引用
收藏
页码:621 / 631
页数:11
相关论文
共 10 条
[1]  
BRZYSKA W, 1996, LANTHANIDES ACTINIDE
[2]  
BUJONEK B, 1989, CHEM ANAL-WARSAW, V34, P391
[3]  
Czerminski J. B., 1992, STAT METHODS CHEM
[4]   A MODIFIED AND A NEW STRAIGHT-LINE METHOD FOR DETERMINING COMPOSITION OF WEAK COMPLEXES OF FORM AMBN [J].
HOLME, A ;
LANGMYHR, FJ .
ANALYTICA CHIMICA ACTA, 1966, 36 (03) :383-&
[5]  
INCZEDY J, 1979, COMPLEXATION EQUILIB
[6]   APPLICABILITY OF STRAIGHT-LINE METHOD OF ASMUS IN DETERMINATION OF COMPOSITION OF POLYNUCLEAR COMPLEXES [J].
KLAUSEN, KS ;
LANGMYHR, FJ .
ANALYTICA CHIMICA ACTA, 1963, 28 (06) :501-&
[7]   COMPLEXES OF PR3+, ND3+, EU3+, GD3+, DY3+, AND ER3+ IONS WITH QUERCETIN-5'-SULFONIC ACID [J].
KOPACZ, M ;
NOWAK, D .
MICROCHEMICAL JOURNAL, 1993, 47 (03) :338-344
[8]  
KOPACZ M, 1982, PRACE NAUK I CHEM NI, V21
[9]  
ROSSOTTI H, 1983, IONS EQUILIBRIA
[10]  
TERPILOW.J, 1970, DISSERT PHARM PHARMA, V22, P389