The fluorine atom as a halogen bond donor, viz. a positive site

被引：212

作者：

Metrangolo, Pierangelo ^{[1
,2
]}

Murray, Jane S. ^{[3
]}

Pilati, Tullio ^{[1
,4
]}

Politzer, Peter ^{[3
]}

Resnati, Giuseppe ^{[1
,2
]}

Terraneo, Giancarlo ^{[1
,2
]}

机构：

[1] Politecn Milan, NFMLab, Dept Chem Mat & Chem Engn, I-20131 Milan, Italy

[2] CNST IIT POLIMI, I-20133 Milan, Italy

[3] CleveTheoComp, Cleveland, OH 44113 USA

[4] Univ Milan, ISTM CNR, I-20133 Milan, Italy

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 22期

关键词：

RAMAN-SPECTRA; COMPLEXES; CRYSTAL; ION;

D O I：

10.1039/c1ce05554b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When bound to residues which can work as particularly strong electron withdrawing groups, fluorine can display a region of positive electrostatic potential (positive sigma-hole). Fluorine can thus function as a halogen bond donor and form complexes with lone-pair-containing neutral atoms and anions. Examples in the gas, liquid, and solid phases are discussed.

引用

页码：6593 / 6596

页数：4

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