SBA-15 derived carbon-supported SnO2 nanowire arrays with improved lithium storage capabilities

被引:61
作者
Ding, Shujiang [1 ]
Wang, Zhiyu [1 ,2 ]
Madhavi, Srinivasan [2 ]
Lou, Xiong Wen [1 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
新加坡国家研究基金会;
关键词
MESOPOROUS SILICA; HOLLOW NANOSPHERES; NANOPARTICLES; COMPOSITE; MICROSPHERES; NANOTUBES; COPOLYMER; TRIBLOCK;
D O I
10.1039/c1jm11902h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we report a facile strategy for the synthesis of carbon-supported SnO2 nanowire arrays using SBA-15 nanorods as template. In the first step, molten SnCl2 center dot 2H(2)O is efficiently infiltrated into the channels of SBA-15 nanorods. After calcination and further removal of the silica template, SnO2 nanowire arrays are obtained with a high yield. Then amorphous carbon is deposited onto the interstitial space of these SnO2 nanowire arrays by a facile hydrothermal method followed by subsequent calcination under an inert atmosphere. When the resultant carbon-supported SnO2 nanowire arrays are evaluated as potential anode materials for lithium-ion-batteries (LIBs), they exhibit relatively high capacities with excellent capacity retention.
引用
收藏
页码:13860 / 13864
页数:5
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