NHC/Iron cooperative catalysis: aerobic oxidative esterification of aldehydes with phenols

被引：94
|
作者：
Reddy, R. Sudarshan [1 ]
Rosa, Joao N. [1 ]
Veiros, Luis F. [2 ]
Caddick, Stephen [3 ]
Gois, Pedro M. P. [1 ]
机构：
[1] Univ Lisbon, Fac Pharm, Res Inst Med & Pharmaceut Sci iMed UL, P-1649003 Lisbon, Portugal
[2] Inst Super Tecn, Ctr Quim Estrutural, Dept Engn Quim & Biol, P-1049001 Lisbon, Portugal
[3] UCL, Dept Chem, London, England
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 09期
关键词：
N-HETEROCYCLIC CARBENES; ALPHA; BETA-UNSATURATED ALDEHYDES; ACTIVATED CARBOXYLATES; IRON; GENERATION; ESTERS; METAL; AMIDATION; ALCOHOLS; ENALS;
D O I：
10.1039/c1ob05151b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An NHC/iron cooperative catalytic system mediates the aerobic oxidative esterification of aldehydes with phenols. The use of equimolar amounts of reactants led to good to excellent isolated yields of esters.
引用
收藏
页码：3126 / 3129
页数：4
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