Aqueous Dye-Sensitized Solar Cell Electrolytes Based on the Ferricyanide-Ferrocyanide Redox Couple

被引：96

作者：

Daeneke, Torben ^{[2
,3
]}

Uemura, Yu ^{[4
,5
]}

Duffy, Noel W. ^{[6
]}

Mozer, Attila J. ^{[7
,8
]}

Koumura, Nagatoshi ^{[4
,5
]}

Bach, Udo ^{[1
]}

Spiccia, Leone ^{[2
,3
]}

机构：

[1] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Monash Univ, ARC Ctr Excellence Electromat Sci, Clayton, Vic 3800, Australia

[4] Natl Inst Adv Ind Sci & Technol, Res Inst Photovolta Technol, Tsukuba, Ibaraki 3058565, Japan

[5] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[6] CSIRO Energy Technol, Clayton, Vic 3169, Australia

[7] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

[8] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 09期

基金：

澳大利亚研究理事会;

关键词：

dye-sensitized solar cell; ferrocyanide redox couple; aqueous electrolyte; energy conversion; organic and inorganic dyes; CHARGE RECOMBINATION; ORGANIC-DYES; EFFICIENCY; FILMS;

D O I：

10.1002/adma.201104837

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solar energy conversion efficiencies of over 4% have been achieved in DSCs constructed with aqueous electrolytes based on the ferricyanide-ferrocyanide redox couple, thereby avoiding the use of expensive, flammable and toxic solvents. This paradigm shift was made possible by the use of a hydrophobic organic carbazole dye. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1222 / 1225

页数：4

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