UV-irradiated sol-gel spin coated AZO thin films: enhanced optoelectronic properties

被引:17
作者
Khan, Md. Irfan [1 ]
Neha, Tasratur Reaj [1 ]
Billah, Md. Muktadir [1 ]
机构
[1] Bangladesh Univ Engn & Technol, Dept Mat & Met Engn, Dhaka 1000, Bangladesh
关键词
Thin film; Sol-gel; Optoelectronic; Burstein-moss effect; UV irradiation; UV blocking; OPTICAL-PROPERTIES; SPRAY-PYROLYSIS; ZNO; TRANSPARENT; CONDUCTIVITY; ORIENTATION; TEMPERATURE; FIGURE; MERIT;
D O I
10.1016/j.heliyon.2022.e08743
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Thin films of transparent conductive Al doped ZnO (AZO) thin films were produced via sol-gel spin coating route. Structural, optical, and electrical properties were explored for several dopant concentrations. Formation of crystalline AZO was verified by X-ray Diffraction (XRD) Analysis and structural analysis were carried out later from the XRD data. Highest band gap of 3.67 eV was found for 2 mol % AZO thin films. The average transmittance was found to be 84.19% in the visible spectra for the corresponding thin films. 2 mol% AZO also exhibited a minimum resistivity of 2.05 Omega-cm with a maximum value of figure of merit. Prolonged UV irradiation was applied to 2 mol % AZO thin films prior to annealing. It significantly modified the surface morphology of the film and provided shielding near UVA (315-378 nm) spectrum. This also enhanced the conductivity of the thin film by 3-fold compared to non-UV treated sample and decreased optical band gap significantly.
引用
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页数:8
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