Nanopatterning of Fluorinated Graphene by Electron Beam Irradiation

被引:170
作者
Withers, Freddie [1 ]
Bointon, Thomas H. [1 ]
Dubois, Marc [2 ]
Russo, Saverio [1 ]
Craciun, Monica F. [1 ]
机构
[1] Univ Exeter, CEMPS, Ctr Graphene Sci, Exeter EX4 4QL, Devon, England
[2] Clermont Univ, UBP, Lab Mat Inorgan, CNRS,UMR 6002, F-63177 Clermont Ferrand, France
基金
英国工程与自然科学研究理事会;
关键词
Nanopatterning; fluorinated graphene; electron irradiation; electron transport; OXIDE; SEMICONDUCTORS; HYDROGENATION; TRANSISTORS;
D O I
10.1021/nl2020697
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate the possibility to selectively reduce insulating fluorinated graphene to conducting and semiconducting graphene by electron beam irradiation. Electron-irradiated fluorinated graphene microstructures show 7 orders of magnitude decrease in resistivity (from 1 T Omega to 100 k Omega), whereas nanostructures show a transport gap in the source drain bias voltage. In this transport gap, electrons are localized, and charge transport is dominated by variable range hopping. Our findings demonstrate a step forward to all-graphene transparent and flexible electronics.
引用
收藏
页码:3912 / 3916
页数:5
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