An empirical model to evaluate the contribution of alloyed and non-alloyed tin to the ethanol oxidation reaction on Pt-Sn/C catalysts based on the presence of SnO2 and a Pt(1-x)Snx solid solution: Application to DEFC performance

被引：19
作者：
Antolini, Ermete [1 ]
机构：
[1] Scuola Sci Mat, I-16016 Genoa, Italy
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2011年 / 36卷 / 17期
关键词：
Direct ethanol fuel cell; Pt-Sn/C; Electrocatalysts; Particle size; FUEL-CELLS; ELECTROCATALYTIC OXIDATION; PTSN/C CATALYSTS; FORMIC-ACID; ELECTROOXIDATION; REDUCTION; ALCOHOLS; METHANOL;
D O I：
10.1016/j.ijhydene.2011.05.099
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An empirical model is proposed to evaluate the contribution of alloyed and non-alloyed tin in Pt-z-Sn/C catalysts to the performance of direct ethanol fuel cells (DEFCs). The model is based on the presence of SnO2 and a Pt(1-x)Sx solid solution in the bimetallic catalysts. The model predicts the dependence of the performance of a single DEFC on the total Sn content and the degree of alloying of Pt-z-Sn/C catalysts used as the anode material. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：11043 / 11047
页数：5
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