Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine -: X-ray crystal structure of the polymeric Cd(II) complex

被引：30

作者：

Miodragovic, Djenana U. ^{[1
]}

Mitic, Dragana M. ^{[2
]}

Miodragovic, Zoran M. ^{[1
]}

Bogdanovic, Goran A. ^{[3
]}

Vitnik, Zeljko J. ^{[1
]}

Vitorovic, Maja D. ^{[1
]}

Radulovic, Milanka D. ^{[4
]}

Nastasijevic, Branislav J. ^{[1
]}

Juranic, Ivan O. ^{[1
]}

Andelkovic, Katarina K. ^{[1
]}

机构：

[1] Univ Belgrade, Fac Chem, Belgrade 11000, Serbia

[2] Univ Belgrade, Fac Stomatol, Belgrade 11000, Serbia

[3] Vinca Inst Nucl Sci, Lab Theoret Phys & Condensed Matter Phys, Belgrade 11000, Serbia

[4] Univ Belgrade, Inst Chem Technol & Met, Dept Chem, Belgrade 11000, Serbia

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 01期

关键词：

zinc(II); cadmium(II) and cobalt(II) complexes; N-Boc-glycine; X-ray; DFT; microbiological assay;

D O I：

10.1016/j.ica.2007.06.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：86 / 94

页数：9

共 55 条

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