Thermal and structural behavior of Buriti oil/poly(methyl methacrylate) and Buriti oil/polystyrene materials

被引:11
作者
Duraes, Jussara A. [1 ]
Drummond, Adriana L. [1 ]
Pimentel, T. A. P. F. [1 ]
Murta, Maria M. [2 ]
Moreira, S. G. C. [3 ]
Sales, Maria J. A. [1 ]
机构
[1] Univ Brasilia, Inst Quim, Lab Pesquisa Polimeros LabPol, BR-70904970 Brasilia, DF, Brazil
[2] Univ Brasilia, Inst Quim, Lab Isolamento & Transformacao Mol Organ, BR-70904970 Brasilia, DF, Brazil
[3] Fed Univ Para, Dept Fis, BR-66075900 Belem, Para, Brazil
关键词
Buriti oil; polymer additives; poly(methyl methacrylate); polystyrene;
D O I
10.1007/s10973-007-8564-z
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports the thermal and structural changes promoted by Buriti (Mauritia flexuosa L.) oil incorporation into polystyrene (PS) and poly(methyl methacrylate) (PMMA) matrices. Buriti oil, which was used due to its high beta-carotene content has a good thermal stability and can provide some stability to PS and PMMA as it was shown by TG and TMA data. DSC results showed that both PMMA and PS-based materials were plasticized by the oil and demonstrated that they are immiscible materials. SEM images depict the materials' morphology.
引用
收藏
页码:529 / 534
页数:6
相关论文
共 13 条
[1]  
Albuquerque MLS, 2005, J BRAZIL CHEM SOC, V16, P1113
[2]   Thermal diffusivity measurements in vegetable oils with thermal lens technique [J].
Bernal-Alvarado, J ;
Mansanares, AM ;
da Silva, EC ;
Moreira, SGC .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2003, 74 (01) :697-699
[3]   Measurements of temperature and melting heat of some pure fatty acids and their binary and ternary mixtures by differential scanning calorimetry [J].
Cedeño, FO ;
Prieto, MM ;
Espina, A ;
García, JR .
THERMOCHIMICA ACTA, 2001, 369 (1-2) :39-50
[4]  
de França LF, 1999, J SUPERCRIT FLUID, V14, P247
[5]   Absorption and photoluminescence of Buriti oil/polystyrene and Buriti oil/poly(methyl methacrylate) blends [J].
Duraes, J. A. ;
Drummond, A. L. ;
Pimentel, T. A. P. F. ;
Murta, M. M. ;
Bicalho, F. da S. ;
Moreira, S. G. C. ;
Sales, M. J. A. .
EUROPEAN POLYMER JOURNAL, 2006, 42 (12) :3324-3332
[6]   Observation of negative differential resistance and hysteretic effect on buriti oil:polystyrene organic devices [J].
Duraes, J. A. ;
Sales, M. J. Araujo ;
Souto, R. F. ;
Romariz, A. ;
da Costa, J. C. ;
Ceschin, A. M. ;
Moreira, S. G. C. .
APPLIED PHYSICS LETTERS, 2006, 89 (13)
[7]   Physical and chemical analysis of dielectric properties and differential scanning calorimetry techniques on buriti oil [J].
Garcia-Quiroz, A ;
Moreira, SGC ;
de Morais, AV ;
Silva, AS ;
da Rocha, GN ;
Alcantara, P .
INSTRUMENTATION SCIENCE & TECHNOLOGY, 2003, 31 (01) :93-101
[8]   Coconut oil as base oil for industrial lubricants - evaluation and modification of thermal, oxidative and low temperature properties [J].
Jayadas, N. H. ;
Nair, K. Prabhakaran .
TRIBOLOGY INTERNATIONAL, 2006, 39 (09) :873-878
[9]   Enhancement of thermal stability of polystyrene and poly(methyl methacrylate) by cyclotriphosphazene derivatives [J].
Muraki, T ;
Ueta, M ;
Ihara, E ;
Inoue, K .
POLYMER DEGRADATION AND STABILITY, 2004, 84 (01) :87-93
[10]   Studies in the utilisation of epoxidised vegetable oils as thermal stabiliser for polyvinyl chloride [J].
Okieimen, FE .
INDUSTRIAL CROPS AND PRODUCTS, 2002, 15 (01) :71-75